NCERT Solutions for Class 12 Chemistry Chapter 3 Electrochemistry are provided here with simple step-by-step explanations. These solutions for Electrochemistry are extremely popular among class 12 students for Chemistry Electrochemistry Solutions come handy for quickly completing your homework and preparing for exams. All questions and answers from the NCERT Book of class 12 Chemistry Chapter 3 are provided here for you for free. You will also love the ad-free experience on Meritnation’s NCERT Solutions. All NCERT Solutions for class 12 Chemistry are prepared by experts and are 100% accurate.
Page No 68:
Question 3.1:
How would you determine the standard electrode potential of the systemMg2+ | Mg?
Answer:
The standard electrode potential of Mg2+ | Mg can be measured with respect to the standard hydrogen electrode, represented by Pt(s), H2(g) (1 atm) | H+(aq)(1 M).
A cell, consisting of Mg | MgSO4 (aq 1 M) as the anode and the standard hydrogen electrode as the cathode, is set up.
Then, the emf of the cell is measured and this measured emf is the standard electrode potential of the magnesium electrode.
Here,
for the standard hydrogen electrode is zero.
∴
Page No 68:
Question 3.2:
Can you store copper sulphate solutions in a zinc pot?
Answer:
Zinc is more reactive than copper. Therefore, zinc can displace copper from its salt solution. If copper sulphate solution is stored in a zinc pot, then zinc will displace copper from the copper sulphate solution.
Hence, copper sulphate solution cannot be stored in a zinc pot.
Page No 68:
Question 3.3:
Consult the table of standard electrode potentials and suggest three substances that can oxidise ferrous ions under suitable conditions.
Answer:
Substances that are stronger oxidising agents than ferrous ions can oxidise ferrous ions.
;
= −0.77 V
This
implies that the substances having higher
reduction potentials than
+0.77 V can oxidise ferrous ions to
ferric ions. Three substances that can do so are F2,
Cl2,
and O2.
Page No 73:
Question 3.4:
Calculate the potential of hydrogen electrode in contact with a solution whose pH is 10.
Answer:
For
hydrogen electrode,
,
it is given that pH = 10
∴[H+] = 10−10 M
Now, using Nernst equation:
=
= −0.0591 log 1010
= −0.591 V
Page No 73:
Question 3.5:
Calculate the emf of the cell in which the following reaction takes place:
Given
that
=
1.05 V
Answer:
Applying Nernst equation we have:
= 1.05 − 0.02955 log 4 × 104
= 1.05 − 0.02955 (log 10000 + log 4)
= 1.05 − 0.02955 (4 + 0.6021)
= 0.914 V
Page No 73:
Question 3.6:
The cell in which the following reactions occurs:
has
=
0.236 V at 298 K.
Calculate the standard Gibbs energy and the equilibrium constant of the cell reaction.
Answer:
Here,
n = 2,
T = 298 K
We know that:
= −2 × 96487 × 0.236
= −45541.864 J mol−1
= −45.54 kJ mol−1
Again,
−2.303RT
log Kc
= 7.981
∴Kc = Antilog (7.981)
= 9.57 × 107
Page No 84:
Question 3.7:
Why does the conductivity of a solution decrease with dilution?
Answer:
The conductivity of a solution is the conductance of ions present in a unit volume of the solution. The number of ions (responsible for carrying current) decreases when the solution is diluted. As a result, the conductivity of a solution decreases with dilution.
Page No 84:
Question 3.8:
Suggest a way to determine the
value
of water.
Answer:
Applying Kohlrausch’s law of independent migration of ions,
the
value
of water can be determined as follows:
Hence, by knowing the
values
of HCl, NaOH, and NaCl, the
value
of water can be determined.
Page No 84:
Question 3.9:
The molar conductivity of 0.025 mol L−1 methanoic acid is
46.1 S cm2 mol−1.
Calculate its degree of dissociation and dissociation constant. Given λ °(H+)
= 349.6 S cm2 mol−1 and λ °(HCOO−) = 54.6 S cm2 mol
Answer:
C = 0.025 mol L−1
Now, degree of dissociation:
Thus, dissociation constant:
Page No 87:
Question 3.10:
If a current of 0.5 ampere flows through a metallic wire for 2 hours, then how many electrons would flow through the wire?
Answer:
I = 0.5 A
t = 2 hours = 2 × 60 × 60 s = 7200 s
Thus, Q = It
= 0.5 A × 7200 s
= 3600 C
We know that
number of electrons.
Then,
Hence,
number
of electrons will flow through the wire.
Page No 87:
Question 3.11:
Suggest a list of metals that are extracted electrolytically.
Answer:
Metals that are on the top of the reactivity series such as sodium, potassium, calcium, lithium, magnesium, aluminium are extracted electrolytically.
Page No 87:
Question 3.12:
What is the quantity of electricity in coulombs needed to reduce 1 mol of
?
Consider the reaction:
Answer:
The given reaction is as follows:
Therefore, to reduce 1
mole of
,
the required quantity of electricity will be:
=6 F
= 6 × 96487 C
= 578922 C
Page No 91:
Question 3.13:
Write the chemistry of recharging the lead storage battery, highlighting all the materials that are involved during recharging.
Answer:
A lead storage battery consists of a lead anode, a grid of lead packed with lead oxide (PbO2) as the cathode, and a 38% solution of sulphuric acid (H2SO4) as an electrolyte.
When the battery is in use, the following cell reactions take place:
At anode:
At cathode:
The overall cell reaction is given by,
When a battery is charged, the reverse of all these reactions takes place.
Hence, on charging,
present at the anode and cathode is converted into
and
respectively.
Page No 91:
Question 3.14:
Suggest two materials other than hydrogen that can be used as fuels in fuel cells.
Answer:
Methane and methanol can be used as fuels in fuel cells.
Page No 91:
Question 3.15:
Explain how rusting of iron is envisaged as setting up of an electrochemical cell.
Answer:
In the process of corrosion, due to the presence of air and moisture, oxidation takes place at a particular spot of an object made of iron. That spot behaves as the anode. The reaction at the anode is given by,
Electrons released at the anodic spot move through the metallic object and go to another spot of the object.
There, in the presence of H+ ions, the electrons reduce oxygen. This spot behaves as the cathode. These H+ ions come either from H2CO3, which are formed due to the dissolution of carbon dioxide from air into water or from the dissolution of other acidic oxides from the atmosphere in water.
The reaction corresponding at the cathode is given by,
The overall reaction is:
Also, ferrous ions are
further oxidized by atmospheric oxygen to ferric ions. These ferric
ions combine with moisture, present in the surroundings, to form
hydrated ferric oxidei.e.,
rust.
Hence, the rusting of iron is envisaged as the setting up of an electrochemical cell.
Page No 92:
Question 3.1:
Arrange the following metals in the order in which they displace each other from the solution of their salts.
Al, Cu, Fe, Mg and Zn
Answer:
The following is the order in which the given metals displace each other from the solution of their salts.
Mg, Al, Zn, Fe, Cu
Page No 92:
Question 3.2:
Given the standard electrode potentials,
K+/K = −2.93V, Ag+/Ag = 0.80V,
Hg2+/Hg = 0.79V
Mg2+/Mg = −2.37 V, Cr3+/Cr = − 0.74V
Arrange these metals in their increasing order of reducing power.
Answer:
The lower the reduction potential, the higher is the reducing power. The given standard electrode potentials increase in the order of K+/K < Mg2+/Mg < Cr3+/Cr < Hg2+/Hg < Ag+/Ag.
Hence, the reducing power of the given metals increases in the following order:
Ag < Hg < Cr < Mg < K
Page No 92:
Question 3.3:
Depict the galvanic cell in which the reaction Zn(s) + 2Ag+(aq) → Zn2+(aq) + 2Ag(s) takes place. Further show:
(i) Which of the electrode is negatively charged?
(ii) The carriers of the current in the cell.
(iii) Individual reaction at each electrode.
Answer:
The galvanic cell in which the given reaction takes place is depicted as:
(i) Zn electrode (anode) is negatively charged.
(ii) Ions are carriers of current in the cell and in the external circuit, current will flow from silver to zinc.
(iii) The reaction taking place at the anode is given by,
The reaction taking place at the cathode is given by,
Page No 92:
Question 3.4:
Calculate the standard cell potentials of galvanic cells in which the following reactions take place:
(i) 2Cr(s) + 3Cd2+(aq) → 2Cr3+(aq) + 3Cd
(ii) Fe2+(aq) + Ag+(aq) → Fe3+(aq) + Ag(s)
Calculate the ΔrGθ and equilibrium constant of the reactions.
Answer:
(i)
The galvanic cell of the given reaction is depicted as:
Now, the standard cell potential is
In the given equation,
n = 6
F = 96487 C mol−1
= +0.34 V
Then,
= −6 × 96487 C mol−1 × 0.34 V
= −196833.48 CV mol−1
= −196833.48 J mol−1
= −196.83 kJ mol−1
Again,
= −RT ln K
= 34.496
K = antilog (34.496)
= 3.13 × 1034
(ii)
The galvanic cell of the given reaction is depicted as:
Now, the standard cell potential is
Here, n = 1.
Then,
= −1 × 96487 C mol−1 × 0.03 V
= −2894.61 J mol−1
= −2.89 kJ mol−1
Again,
= 0.5073
K
= antilog (0.5073)
= 3.2 (approximately)
Page No 92:
Question 3.5:
Write the Nernst equation and emf of the following cells at 298 K:
(i) Mg(s) | Mg2+(0.001M) || Cu2+(0.0001 M) | Cu(s)
(ii) Fe(s) | Fe2+(0.001M) || H+(1M)|H2(g)(1bar) | Pt(s)
(iii) Sn(s) | Sn2+(0.050 M) || H+(0.020 M) | H2(g) (1 bar) | Pt(s)
(iv) Pt(s) | Br2(l) | Br−(0.010 M) || H+(0.030 M) | H2(g) (1 bar) | Pt(s).
Answer:
(i) For the given reaction, the Nernst equation can be given as:
= 2.7 − 0.02955
= 2.67 V (approximately)
(ii) For the given reaction, the Nernst equation can be given as:
= 0.52865 V
= 0.53 V (approximately)
(iii) For the given reaction, the Nernst equation can be given as:
= 0.14 − 0.0295 × log125
= 0.14 − 0.062
= 0.078 V
= 0.08 V (approximately)
(iv) For the given reaction, the Nernst equation can be given as:
Page No 93:
Question 3.6:
In the button cells widely used in watches and other devices the following reaction takes place:
Zn(s) + Ag2O(s) + H2O(l) → Zn2+(aq) + 2Ag(s) + 2OH−(aq)
Determine
and
for the reaction.
Answer:
=
1.104 V
We know that,
= −2 × 96487 × 1.04
= −213043.296 J
= −213.04 kJ
Page No 93:
Question 3.7:
Define conductivity and molar conductivity for the solution of an electrolyte. Discuss their variation with concentration.
Answer:
Conductivity of a solution is defined as the conductance of a solution of 1 cm in length and area of cross-section 1 sq. cm. The inverse of resistivity is called conductivity or specific conductance. It is represented by the symbolκ. If ρ is resistivity, then we can write:
The conductivity of a solution at any given concentration is the conductance (G) of one unit volume of solution kept between two platinum electrodes with the unit area of cross-section and at a distance of unit length.
i.e.,
(Since a = 1, l = 1)
Conductivity always decreases with a decrease in concentration, both for weak and strong electrolytes. This is because the number of ions per unit volume that carry the current in a solution decreases with a decrease in concentration.
Molar conductivity:
Molar conductivity of a solution at a given concentration is the conductance of volume V of a solution containing 1 mole of the electrolyte kept between two electrodes with the area of cross-section A and distance of unit length.
Now, l = 1 and A = V (volume containing 1 mole of the electrolyte).
Molar conductivity increases with a decrease in concentration. This is because the total volume V of the solution containing one mole of the electrolyte increases on dilution.
The variation of
with
for
strong and weak electrolytes is shown in the following plot:
Page No 93:
Question 3.8:
The conductivity of 0.20 M solution of KCl at 298 K is 0.0248 Scm−1. Calculate its molar conductivity.
Answer:
Given,
κ = 0.0248 S cm−1
c = 0.20 M
Molar conductivity,
= 124 Scm2mol−1
Page No 93:
Question 3.9:
The resistance of a conductivity cell containing 0.001M KCl solution at 298 K is 1500 Ω. What is the cell constant if conductivity of 0.001M KCl solution at 298 K is 0.146 × 10−3 S cm−1.
Answer:
Given,
Conductivity, κ = 0.146 × 10−3 S cm−1
Resistance, R = 1500 Ω
Cell constant = κ × R
= 0.146 × 10−3 × 1500
= 0.219 cm−1
Page No 93:
Question 3.10:
The conductivity of sodium chloride at 298 K has been determined at different concentrations and the results are given below:
Concentration/M 0.001 0.010 0.020 0.050 0.100
102 × κ/S m−1 1.237 11.85 23.15 55.53 106.74
Calculate
for all concentrations and draw a
plot between
and
c½. Find the value of
.
Answer:
Given,
κ = 1.237 × 10−2 S m−1, c = 0.001 M
Then, κ = 1.237 × 10−4 S cm−1,c½ = 0.0316 M1/2
= 123.7 S cm2 mol−1
Given,
κ = 11.85 × 10−2 S m−1, c = 0.010M
Then, κ = 11.85 × 10−4 S cm−1, c½ = 0.1 M1/2
= 118.5 S cm2 mol−1
Given,
κ = 23.15 × 10−2 S m−1, c = 0.020 M
Then, κ = 23.15 × 10−4 S cm−1, c1/2 = 0.1414 M1/2
= 115.8 S cm2 mol−1
Given,
κ = 55.53 × 10−2 S m−1, c = 0.050 M
Then, κ = 55.53 × 10−4 S cm−1, c1/2 = 0.2236 M1/2
= 111.1 1 S cm2 mol−1
Given,
κ = 106.74 × 10−2 S m−1, c = 0.100 M
Then, κ = 106.74 × 10−4 S cm−1, c1/2 = 0.3162 M1/2
= 106.74 S cm2 mol−1
Now, we have the following data:
-
0.0316
0.1
0.1414
0.2236
0.3162
123.7
118.5
115.8
111.1
106.74
Since the line
interruptsat
124.0 S cm2 mol−1,
=
124.0 S cm2 mol−1.
Page No 93:
Question 3.11:
Conductivity
of 0.00241 M acetic acid is 7.896 × 10−5
S cm−1.
Calculate its molar conductivity and if
for
acetic acid is 390.5 S cm2
mol−1,
what is its dissociation constant?
Answer:
Given, κ = 7.896 × 10−5 S m−1
c = 0.00241 mol L−1
Then, molar
conductivity,
= 32.76S cm2 mol−1
Again,
= 390.5 S cm2 mol−1
Now,
= 0.084
Dissociation
constant,
= 1.86 × 10−5 mol L−1
Page No 93:
Question 3.12:
How much charge is required for the following reductions:
(i) 1 mol of Al3+ to Al.
(ii) 1 mol of Cu2+ to Cu.
(iii)
1 mol of
to Mn2+.
Answer:
(i)
Required charge = 3 F
= 3 × 96487 C
= 289461 C
(ii)
Required
charge = 2 F
= 2 × 96487 C
= 192974 C
(iii)
i.e.,
Required charge = 5 F
= 5 × 96487 C
= 482435 C
Page No 93:
Question 3.13:
How much electricity in terms of Faraday is required to produce
(i) 20.0 g of Ca from molten CaCl2.
(ii) 40.0 g of Al from molten Al2O3.
Answer:
(i) According to the question,
Electricity required to produce 40 g of calcium = 2 F
Therefore,
electricity required to produce 20 g of calcium
= 1 F
(ii) According to the question,
Electricity required to produce 27 g of Al = 3 F
Therefore,
electricity required to produce 40 g of Al
= 4.44 F
Page No 93:
Question 3.14:
How much electricity is required in coulomb for the oxidation of
(i) 1 mol of H2O to O2.
(ii) 1 mol of FeO to Fe2O3.
Answer:
(i) According to the question,
Now, we can write:
Electricity required for the oxidation of 1 mol of H2O to O2 = 2 F
= 2 × 96487 C
= 192974 C
(ii) According to the question,
Electricity required for the oxidation of 1 mol of FeO to Fe2O3 = 1 F
= 96487 C
Page No 93:
Question 3.15:
A solution of Ni(NO3)2 is electrolysed between platinum electrodes using a current of 5 amperes for 20 minutes. What mass of Ni is deposited at the cathode?
Answer:
Given,
Current = 5A
Time = 20 × 60 = 1200 s
Charge
= current × time
= 5 × 1200
= 6000 C
According to the reaction,
Nickel deposited by 2 × 96487 C = 58.71 g
Therefore, nickel
deposited by 6000 C
= 1.825 g
Hence, 1.825 g of nickel will be deposited at the cathode.
Page No 93:
Question 3.16:
Three electrolytic cells A,B,C containing solutions of ZnSO4, AgNO3 and CuSO4, respectively are connected in series. A steady current of 1.5 amperes was passed through them until 1.45 g of silver deposited at the cathode of cell B. How long did the current flow? What mass of copper and zinc were deposited?
Answer:
According to the reaction:
i.e., 108 g of Ag is deposited by 96487 C.
Therefore, 1.45 g of Ag
is deposited by =
= 1295.43 C
Given,
Current = 1.5 A
Time
= 863.6 s
= 864 s
= 14.40 min
Again,
i.e., 2 × 96487 C of charge deposit = 63.5 g of Cu
Therefore, 1295.43 C of
charge will deposit
= 0.426 g of Cu
i.e., 2 × 96487 C of charge deposit = 65.4 g of Zn
Therefore, 1295.43 C of
charge will deposit
= 0.439 g of Zn
Page No 93:
Question 3.17:
Using the standard electrode potentials given in Table 3.1, predict if the reaction between the following is feasible:
(i) Fe3+(aq) and I−(aq)
(ii) Ag+ (aq) and Cu(s)
(iii) Fe3+ (aq) and Br− (aq)
(iv) Ag(s) and Fe3+ (aq)
(v) Br2 (aq) and Fe2+ (aq).
Answer:
Sincefor
the overall reaction is positive, the reaction between Fe3+(aq)
and I−(aq)
is feasible.
Since
for the overall reaction is positive, the reaction between Ag+
(aq) and Cu(s)
is feasible.
Since
for the overall reaction is negative, the reaction between Fe3+(aq)
and Br−(aq)
is not feasible.
Since
E
for the overall reaction is negative, the reaction between Ag
(s) and Fe3+(aq)
is not feasible.
Since
for the overall reaction is positive, the reaction between Br2(aq)
and Fe2+(aq) is
feasible.
Page No 94:
Question 3.18:
Predict the products of electrolysis in each of the following:
(i) An aqueous solution of AgNO3 with silver electrodes.
(ii) An aqueous solution of AgNO3with platinum electrodes.
(iii) A dilute solution of H2SO4with platinum electrodes.
(iv) An aqueous solution of CuCl2 with platinum electrodes.
Answer:
(i) At cathode:
The following reduction reactions compete to take place at the cathode.
The
reaction with a higher value of
takes place at the cathode. Therefore, deposition of silver will take
place at the cathode.
At anode:
The
Ag anode is attacked by
ions.
Therefore, the silver electrode at the anode dissolves in the
solution to form Ag+.
(ii) At cathode:
The following reduction reactions compete to take place at the cathode.
The
reaction with a higher value of
takes place at the cathode. Therefore, deposition of silver will take
place at the cathode.
At anode:
Since
Pt electrodes are inert, the anode is not attacked by
ions. Therefore, OH− or
ions can be oxidized at the anode. But OH− ions
having a lower discharge potential and get preference and decompose
to liberate O2.
(iii) At the cathode, the following reduction reaction occurs to produce H2 gas.
At the anode, the following processes are possible.
For dilute sulphuric acid, reaction (i) is preferred to produce O2 gas. But for concentrated sulphuric acid, reaction (ii) occurs.
(iv) At cathode:
The following reduction reactions compete to take place at the cathode.
The
reaction with a higher value of
takes place at the cathode. Therefore, deposition of copper will take
place at the cathode.
At
anode:
The following oxidation reactions are possible at the
anode.
At
the anode, the reaction with a lower value of
is preferred. But due to the over-potential of oxygen, Cl−
gets oxidized at the anode to produce Cl2 gas.
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