Which one of the following parirs would have a larger size ? explain
1) O2 - or F-
2) P or As

Dear Student,

1) They both are isoelectronic species. Therefore only charge will decide the size of atom. Greater the negative charge, greater will the size of anion. Therefore,
O2- > F-.

2) Size of atom increases on going from top to bottom in a group due to decrease in effective nuclear charge. Therefore,
As > P

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1. O2_ and F_ are isoelectronic  species. since effective nuclear charge  of O2_ is lower than that of F_, therefore , O2_
​has higher atomic size than F_. 
2. As has four shell while P has three . therefore atomic size of As is higher than of P.
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